江西省高校重点学科―物理化学

物理化学重点学科的主要研究方向包括:(1)功能配合物研究------主持人:曾锡瑞教授①具有特征荧光的稀土配合物(如Eu3+Complexes)的制备和性质研究.为设计合成具有特殊结构和性能的金属有机配合物提供理论依据,并且有利于从整体上提高对金属有机配合物研究的理论水平。 

我院物理化学学科是江西省高等学校“十五”、“十一五”和“十二五”重点学科。现任学科带头人黄俭根博士、教授。井冈山大学作为一所“省部共建”高校,责无旁贷承担着服务地方经济社会发展的重任。本学科的研究与“鄱阳湖生态经济区”和“井冈山经济技术开发区”产业发展密切相关。在多年的学科建设过程中,尤其在新型材料、生物医药、林产化工等战略性新兴产业中,发挥了积极作用。

本学科紧密围绕物质结构与性能的关系,已经形成了三个富有特色的研究方向,即:理论与计算化学、材料微结构化学和催化化学及应用。在理论与计算化学方向,利用量子化学方法开展了分子基光、电、磁等功能材料的理论和实验研究,拓宽了分子层面功能材料设计与合成的新途径;在材料微结构化学方向,利用X-射线单晶衍射等方法对有机锡化合物、卟啉光伏材料配位聚合物材料的微观结构和性能关系开展了深入的研究,获得了一批结构新颖、性能优异的新型功能材料;在催化化学及应用方向,本着绿色化学的理念,开展了烯烃环氧化均相催化剂多相化、非经典偶联反应的纳米铜催化等研究,为医药化工、生物制药等行业绿色催化剂的开发提供了新的思路,并在国内外同类研究中产生了较好的影响

本学科具有一支较高水平的研究队伍。通过人才引进和自身培养,已经形成一支学历、学缘、年龄、职称结构合理的,中青年博士为主体的研究团队。本学科现有学科成员16人,其中有教授有4人、副教授9人,具有博士学位的10人、硕士学位的4人,江西省高校教学名师2人,江西省百千万人才工程人选1人,江西省高校中青年学科带头人1人。

本学科拥有一批重要的学科建设平台。通过“十一五”江西省高校重点学科建设,搭建了一批重要的学科建设平台,主要有:江西省配位化学重点实验室,井冈山大学化学重点一级学科,井冈山大学有机化学和分析化学重点建设二级学科。此外,还有国家级化学特色专业,江西省高校基础化学实验教学示范中心,无机化学、有机化学省级精品课程等人才培养平台。

本学科产生了一批有影响的研究成果。近五年来,承担了省(部)级以上科研项目30项,其中国家自然科学基金2项,科技部入园入企项目1项,省自然科学基金项目8项(含青年科学基金3项),省科技厅科技支撑计划项目1项,省科技厅工业攻关计划项目1项,省教育厅科技计划项目15项。这些项目都取得了丰硕的研究成果,已发表研究论文200多篇,其中SCI收录论文100多篇,在材料微结构研究方面,有1篇论文被SCI期刊他引54次,3篇论文曾先后进入国际上相关领域最受关注的前十位论文(TOP 10),在国内外产生了较大的影响。同时,在应用研究方面也取得了较好的突破,近三年来,共申请发明专利13项,已授权发明专利8项,引起了国内外同行的高度关注。

 

部分代表性成果:

1.    Jian-Gen Huang, et al. Density Functional Theory Study on Antiferromagnetic Interactions in a Silver (I) Complex of Nitronyl Nitroxide. J Magn Magn Mater, 2006, 299(2): 480-486.

2.    Xiao-Niu Fang, et al. Synthesis, structure, photoluminescence and theoretical study of (MQ)(CdBr4) with MQ2+ generated in situ (MQ2+ = N –Me-4,4?-bipyridinium). J Iran Chem Soc, 2009, 6(1), 213-218.

3.    Xiao-Niu Fang, et al. Facile Stereoselective Synthesis of (E)-1-Arylseleno-Substituted 1,3-Enynes and Their Applications in Synthesis of (E)-Enediynes. Synth Commun, 2008, 38(23), 4170-4181.

4.    Yan Sui, et al. Discovery of a new type of organic ferroelectric materials in natural biomass dehydroabietylamine Schiff bases, J. Mater. Chem., 2011, 21(38), 14599-14603.

5.    Wen-Tong Chen,et al. A vanadium porphyrin with temperature-dependent phase transformation: Synthesis, crystal structures, supramolecular motifs and properties. Chem.-Asian J., 2011, 6, 1416-1422.

6.    Yan Sui, et al. Ionic ferroelectrics based on nickel Schiff base complexes, Inorg. Chem., 2010, 49(4), 1286-1288Top 10 Articles Published in the Same Domain Since Your Publication

7.    Wen-Tong Chen,et al. Saddle distortion of a sterically unhindered porphyrin ring in a copper porphyrin with electron–donating substituents. Inorg. Chem., 2011, 50, 671-678.

8.    Wen-Tong Chen,et al. X-ray crystal structure of [HSm{VIVO(TPPS)}]n and encapsulation of nitrogen molecules in 1-D channels. Dalton Trans. 2011, 40, 12826-12831. 

9.    Wen-Tong Chen,et al. Cyano-bridged 2D bimetallic 4f-3d arrays with monolayered stair-like, brick-wall-like, or bilayered topologies – rational syntheses and crystal structures. Eur. J. Inorg. Chem., 2010, 2826-2835.

10.  Wen-Tong Chen, et al. Ligand-dependent ultrasonic-assistant self-assemblies and photophysical properties of lanthanide nicotinic/isonicotinic complexes. Inorg. Chem., 2009, 48, 3800-3807.

11.  Dong-Sheng Liu, et al. Two Isomorphous Mn(II) and Co(II) 5-Amino-Tetrazolate Coordination Polymers with Magnetic Δ-Chain: Crystal Structures and Magnetic Properties, Dalton Trans., 2012, DOI:10.1039/C2DT12495E.

12.  Dong-Sheng Liu, et al. Cadmium coordination polymers constructed from in situ generated amino-tetrazole ligand: effect of the conditions on the structures and topologies, Cryst.Growth & Des., 2009, 9(12), 5117-5127.

13.  Wen-Tong Chen, et al. Hydrothermal synthesis, crystal structure and photoluminescence of [HgCl2(C6NO2H5)]n n[HgCl2]n(C6NO2H5). J. Iran. Chem. Soc., 2010,7, 510-515.

14.  Wen-Tong Chen,et al. Syntheses, structures and properties of 3d/5d–4f metal complexes with novel polycationic chains. Inorg. Chim. Acta, 2009, 362, 2379-2385.

15.  Wen-Tong Chen,et al. An unprecedented 2D 4f-3d-5d multimetal-isonicotinic acid complex: synthesis, structural characterization and magnetic properties. Chin. J. Chem., 2008, 26, 1678-1682.

16.  Wen-Tong Chen, et al. [Tb(pyrazincarboxylic acid)3(H2O)2]n?6nH2O: Synthesis, structure and photoluminescence. Z. Kristallogr., 2010,225, 41-45.

17.  Wen-Tong Chen, et al. Synthesis, structure, photoluminescence and theoretical study of {(N, N'-dimethyl-4, 4'-bipyridinium)[Cd2(μ2-Cl)4Cl2]}n with N, N'-dimethyl-4, 4'-bipyridinium generated in situ. J. Iran. Chem. Soc., 2010,7, 180-184..

18.  Yan Sui, et al. A new type of organic ferroelectric material based on maleopimaric acid anhydride, Adv. Mater. Res., 2011, 239-242, 1180-1183.

19.  Yan Sui, et al. Adjustment of the structures and biological activities by the ratio of NiL to RE for two sets of Schiff Base complexes [(NiL)nRE] (n=1 or 2; RE=La or Ce), Inorg. Chem. Commun., 2011, 14(2), 396-398.

20.  Yan Sui, et al. Syntheses, structure, redox and catalytic epoxidation properties of dioxomolybdenum(VI) complexes with Schiff base ligands derived from tris(hydroxymethyl)amino methane, J. Mol. Catal. A:Chem., 2007, 270(1-2), 61-67.

21.  Yan Sui, et al. Grafting polyethylene glycols molybdenum(VI) complexes on ZSPP and their catalytic epoxidation of cyclohexene, Catal. Commun., 2008, 9(15), 2616-2619.

22.  Yan Sui, et al. A new type of heterogeneous epoxidation catalysts polyamines molybdenum(VI) complexes grafted on zirconium oligo-styrenyl phosphonate hydrogen phosphate, Mater. Lett., 2007, 61(6), 1354-1357.

23.  Yan Sui, et al. Preparation, characterization and application of a new type of ion exchanger and solid acid zirconium sulfonated oligo-polystyrenylphosphonate- phosphate supported on ZrO2, J. Mol. Catal. A:Chem., 2004, 217(1-2), 133-138.

24.  Yan Sui, et al. Preparation and properties of solid acid zirconium oligo(sulfostyrenyl) phosphonate hydrogen phosphate supported on TiO2, Mater. Lett.,2005, 59(17), 2115-2119.

25.  Yan Sui, et al. Study of preparation and reaction mechanisms of new types of phosphonous acid-teminated oligostyrene, React. Funct. Polym., 2005, 64(1), 55-62.

26.  Wen-Tong Chen, et al. [{Er(NC5H4COOH)(H2O)2}2(H5O2)(HgCl5)(HgCl4)2(H2O)2]n: Synthesis, crystal structure and photoluminescence. Z. Anorg. Allg. Chem., 2008, 634, 529-533.

27.  Dong-Sheng Liu, et al.Synthesis,  structure and magnetic properties of a two-dimensional manganese(II) complex with a maximum denticity of  ethylenediaminetetraacetic ligandInorg. Chim. Acta2011, 376, 112-117.

28.  Wen-Tong Chen, et al. Change in supramolecular networks through in situ esterification of porphyrins. Eur. J. Inorg. Chem., 2009, 36, 5494-5505.

29.  Dong-Sheng Liu, et al. Synthesis, crystal structures and properties of three new mixed-ligand d10 metal complexes constructed from pyridinecarboxylate and in situ generated amino-tetrazole ligand, J. Solid State Chem., 2009, 182(7), 1899-1906.

30.  Dong-Sheng Liu, et al. Three-dimensional microporous metal–organic framework constructed from Cadmium(II) ion with terephthalate and in-situ generated amino-tetrazole mixed-ligands, Inorg. Chem. Commun., 2010, 13(6), 762-765.

31.  Yin-Feng Wang, et al. Double-cage molecule confines an excess electron in e-@C24F22(NH)2C20F18 and e-@C20F18(NH)2C20F18: the inter-cage electron transition localization. J Phys Chem A, 2010, 114, 11782-11787.

32.  Rong-Hua Hu, et al. MCM-41-supported mercapto platinum complex as a highly efficient catalyst. Catal Commun, 2009, 11(6), 563-566.