功能配合物研究方向

 

 

一、主要研究内容

主要开展以功能材料的设计合成及应用为主题的研究。以江西省内资源丰富的廉价天然生物质资源作为手性源构筑极性空间群化合物,进行铁电、介电以及非线性光学性能等研究,此外还开展了一些功能配合物的光学及催化等性能研究。

二、人员构成:曾锡瑞教授,隋岩教授(博士),陈文通副教授(博士),刘冬生副教授(博士)等。

三、主要承担项目

1、中国博士后科学基金,极性空间群手性二胺衍生配合物的光电功能调控研究,(20090451189),(隋岩主持)

2、江西省教育厅科技项目,新型烯烃环氧化固载催化剂的制备与应用,赣教计字2007317),(隋岩主持)

3江西省教育科学规划课题,大学生学习适应性的特点、影响因素及应对策略研究,(05YB195),(隋岩主持)。

4南京大学配位化学国家重点实验室开放课题,稀土-过渡金属双、多核配合物的合成及性质研究,(隋岩主持):。

5吉安市科技局项目,新型有机-无机混合磷酸锆载体固载烯烃环氧化催化剂的合成、表征及应用研究,(2005028),(隋岩主持)

6江西省教育厅科技项目,以松香类化合物合成新型生物质铁电存储材料的研究,(GJJ10536),(隋岩主持)

7江西省教改课题,开放式大学化学综合设计性实验校本教材开发研究,(JXJG-07-14-9),(隋岩主持)

8江西省自然科学基金,高级烯烃环氧化固载催化剂研究,( 2007GZH1667),(隋岩主持)

9江西省自然科学基金项目,基于松香衍生物的分子基铁电体研究(20114BAB203027),(隋岩主持)

10、国家自然科学基金会,分子金属导线的基础研究(20261004),(曾锡瑞主持)

11、江西省自然科学基金项目,阴离子掺杂碲镉汞法合成新型化合物半导体红外材料,(200007GQH1685),(陈文通主持)。

12、江西省自然科学基金项目,多吡啶胺类功能配合物的基础研究,(0320024),(曾锡瑞主持)

13、 江西省自然(青年)科学基金项目,多核金属功能配合物的制备和结构分析,0520036),(曾锡瑞主持)

14、 江西省自然(青年)科学基金项目,新型半导体红外材料的设计合成、结构和性质研究,(2008GQH0001),(陈文通主持)。

15江西省教育厅科技计划项目,阴离子掺杂法合成新型半导体红外材料,(GJJ08412),(陈文通主持)

16、江西省教育厅科技计划项目,基于对称性破缺原理由非手性基团构建微孔手性多功能材料的合成与性能研究(GJJ12470),(刘冬生主持)

四、主要研究成果

1. Yan Sui, Dong-Ping Li, Cheng-Hui Li, Tao Wu, Xiao-Zeng You, Ionic Ferroelectrics Based on Nickel Schiff Base complexes, Inorg. Chem. 2010, 49(4), 1286-1288.

2. Yan Sui, Xiangkai Fu, Jingrong Chen, Liyang Yin, Grafting polyethylene glycols molybdenum(VI) complexes on ZSPP and their catalytic epoxidation of cyclohexene, Catalysis Communications, 2008, 9(15), 2616-2619

3. Yan Sui, Xirui Zeng, Xiaoniu Fang, Xiangkai Fu, Li Chen, Yi’an Xiao, Menghua Li, Shu Cheng, Syntheses,structure, redox and catalytic epoxidation properties of dioxomolybdenum(VI) complexes with Schiff base ligands derived from tris(hydroxymethyl)amino methane, J. Mol. Catal. A:Chem.,20072701-261-67.

4. Yan Sui, Xiaoniu Fang, Ronghua Hu, Yaping Xu, Xiaochun Zhou, Xiangkai Fu, A new type of heterogeneous epoxidation catalysts polyamines molybdenum(VI) complexes grafted on zirconium oligo-styrenyl phosphonate hydrogen phosphate, Mater. Lett., 2007,61(6), 1354-1357.

5. Sui, Y.; Liu, D. S.; Hu, R. H.; Chen, H. M., Discovery of a new type of organic ferroelectric materials in natural biomass dehydroabietylamine Schiff bases. Journal of Materials Chemistry[J]. 2011, 21 (38), 14599-14603.

6. Sui, Y.; Liu, D. S.; Hu, R. H., A new type of organic ferroelectric material based on maleopimaric acid anhydride. In Advanced Materials, Pts 1-4, Cao, Z.; Cao, X. Q.; Sun, L.; He, Y. H., Eds. 2011; Vol. 239-242, pp 1180-1183.

7. Sui, Y.; Hu, R. H.; Liu, D. S.; Wu, Q., Adjustment of the structures and biological activities by the ratio of NiL to RE for two sets of Schiff Base complexes (NiL)(n)RE (n=1 or 2; RE = La or Ce). Inorganic Chemistry Communications[J]. 2011, 14 (2), 396-398.

8Liu, D. S.; Sui, Y.; Wang, T. W.; Huang, C. C.; Chen, J. Z.; You, X. Z., Two isomorphous Mn(II) and Co(II) 5-amino-tetrazolate coordination polymers with magnetic Delta-chains: crystal structures and magnetic properties. Dalton Transactions[J]. 2012, 41 (17), 5301-5306.

9Liu, D. S.; Sui, Y.; Chen, W. T.; Huang, J. G.; Chen, J. Z.; Huang, C. C., Two new Zn(II) and Cd(II) coordinastion polymers based on amino-tetrazole and phenylcarboxylate: Syntheses, topological structures and photoluminescent properties. J. Solid State Chem.[J]. 2012, 196, 161-167.

10Liu, D. S.; Sui, Y.; Chen, W. T.; Chen, J. Z.; Huang, C. C., Synthesis, structure and luminescence of a hydrogen-bonding helical-chain Cu(II) compound based on (8-quinolinyloxy)acetate. J. Iran Chem. Soc.[J]. 2012, 9 (5), 827-831.

11Chen, W. T., Fluorescent, theoretical and structural investigations on Me(4)bim CdCl4 (Me(4)bim=1,1 ',3,3 '-tetramethyl-2,2 '-bi-1H-imidazolium). Journal of Chemical Research[J]. 2012, (9), 560-562.

12Chen, W. T., Hydrothermal Preparation, Crystal Structure and Properties of { ZnTCPP(EtOH) Zn(en) 2}n(EtOH)2n with a Novel Two-Dimensional (2-D) Motif. Chinese Journal of Chemistry[J]. 2012, 30 (2), 273-276.

13Chen, W. T.; Luo, Z. G.; Chen, H. L.; Kuang, H. M.; Liu, D. S., A novel porphyrin with a two-dimensional topology and highly thermal stability. Journal of Chemical Research[J]. 2012, (2), 72-74.

14Chen, W. T., Synthesis, structure and properties of Pr(C6H5NO2)(3)(H2O)(2) (2n)center dot(nHSO(2))(nHgCl(5))(2nHgCl(4)) (2nH(2)O). Journal of Molecular Structure[J]. 2011, 992 (1-3), 102-105.

15Chen, W. T., SYNTHESIS, STRUCTURE AND PROPERTIES OF A HETEROMETALLIC 4f-5d COMPLEX Sm(Hinic)(3)(H2O)(2) (n)center dot(1.5nHgCl(4))center dot(2nH(2)O). Collection of Czechoslovak Chemical Communications[J]. 2011, 76 (4), 223-234.

16Chen, W. T.; El-Khouly, M. E.; Fukuzumi, S., Saddle Distortion of a Sterically Unhindered Porphyrin Ring in a Copper Porphyrin with Electron-Donating Substituents. Inorganic Chemistry[J]. 2011, 50 (2), 671-678.

17Chen, W. T.; Liu, D. S.; Luo, Z. G.; Chen, H. L.; Liu, J. H., In situ synthesis, X-ray structure, fluorescence and theoretical investigations of Cu2Cl4 (C2H5)(2)-4,4 '-bipyridine. Journal of Chemical Research[J]. 2011, (8), 491-493.

18Chen, W. T.; Luo, Z. G.; Liu, J. H.; Chen, H. L.; Kuang, H. M., Structural and photoluminescent investigations on a zinc porphyrin. Journal of Chemical Research[J]. 2011, (10), 571-573.

19Chen, W. T.; Luo, Z. G.; Xu, Y. P.; Luo, Q. Y.; Liu, J. H., Syntheses, structures and photoluminescence of a series of transition metal-cyanopyridine polymers. Journal of Chemical Research[J]. 2011, (4), 253-256.

20Chen, W. T.; Yamada, Y.; Liu, G. N.; Kubota, A.; Ichikawa, T.; Kojima, Y.; Guo, G. C.; Fukuzumi, S., X-Ray crystal structure of HSm{(VO)-O-IV(TPPS)} (n) and encapsulation of nitrogen molecules in 1-D channels. Dalton Transactions[J]. 2011, 40 (48), 12826-12831.

21Chen, W. T.; Yao, Z. L., Synthesis and characterization of a dysprosium complex with strong photoluminescence. Journal of Coordination Chemistry[J]. 2011, 64 (6), 996-1005.

22Chen, W. T.; Ying, S. M.; Xu, Y. P.; Luo, Q. Y.; Liu, D. S., STRUCTURE AND LUMINESCENCE OF Tb-0.5(C6NO2H5)(3)(H2O)(2) (2n)center dot(H3O)(4n)(ZnCl5)(n)(ZnCl4)(2n). Journal of Structural Chemistry[J]. 2011, 52 (3), 631-634.

五、已授权发明专利

1. 隋岩等,羧酸二乙基二异丙基酯的制备方法及其应用,专利号:ZL 200610155265.4.

2. 隋岩等,羧酸乙基二异丙基酯的制备方法及其应用,专利号:ZL 200610155264.X.

3. 隋岩等,羧酸异丙基二乙基酯的制备方法及其应用,专利号:ZL 200610155263.5.

4. 隋岩等,丙烷-1,2,2,3-四羧酸乙酯作为增塑剂的应用及其制备方法,专利号:ZL 200710051337.5.

5. 隋岩等,乙烷-1,1,2-三羧酸乙酯的制备方法, 专利号:ZL 200710051336.0.