金属有机化学研究方向

  

 

一、主要研究内容

在有机锡化合物,有机钯化合物以及其他过渡金属有机化合物和稀土金属配合物等方面开展一些创新性的基础研究,重点以金属有机化合物的结构分析、药用研究;金属有机化合物参与的合成新方法、金属有机催化剂的研究和开发。 

二、人员构成

方小牛(负责人):教授,江西省高等学校教学名师,江西省化学化工学会常务理事,江西省科技厅、教育厅科技评估专家,2006年获江西省高校科技成果三等奖,主要从事金属有机锡化合物的合成、结构和生物活性研究,已发表第一作者论文50篇,其中SCI收录21

胡荣华:教授,主要从事金属有机化合物的合成与性能研究,已发表学术论文30 多篇,其中SCI 收录近20篇。

隋 岩:副教授,博士后,目前主要从事手性功能配合物的合成与光、电、磁性质研究,已发表SCI收录论文30余篇,获批国家发明专利5项。

唐伯孝:博士,主要从事与金属有机相关的有机合成研究,已在JACSJOCOL等专业期刊上发表研究论文14篇,其中SCI收录12篇。

三、主要承担项目:

1、科技部高校科技人员入园入企项目,一步法合成环保无毒十八烷基芥酸酰胺,(2009GJC50040),(方小牛主持)。

2、江西省自然科学基金项目,新型二茂铁基席夫碱有机锡配合物的合成及应用研究,(2009GZH0063),(方小牛主持)。

3、江西省自然科学基金项目,稀土金属有机锡异核共配物的制备和结构分析,(0620029),(方小牛主持)。

4、江西省自然科学基金项目,新型席夫碱有机锡配合物的合成及生物活性研究,(0320026),(方小牛主持)。

5、江西省教育厅科技计划项目),三唑席夫碱羧酸类有机锡配合物的合成、结构和应用研究,(GJJ09330),(方小牛主持)。

6、南京大学配位化学国家重点实验室开放课题,稀土-过渡金属双、多核配合物的合成及性质研究,(200803),(隋岩主持)。

7、江西省自然科学基金项目,孔状金属-有机骨架化合物的离子热法合成及其催化性能研究(20114BAB203028),(胡荣华主持)。

8、纳米铜催化导向的偶联反应研究(GJJ12471),(唐伯孝主持)。

四、主要研究成果:

1.  Fang XN, et al., Hydrothermal Synthesis, Crystal Structure and Spectroscopic Investigations of [Y(C6NO2H5)3(H2O)2]n(1.5nZnCl4)·nH(2)O with Unprecedented Polycationic Chains. Chemical Research in Chinese Universities, 2008, 24 (5), 529-533.

2.  Fang XN, et al., Synthesis and structure of [Nd(C6NO2H5)3(H2O)2]2n·(3nHgCl4)·(4nH2O). Zeitschrift Fur Kristallographie, 2009, 224 (3), 169-173.

3.  Fang XN, et al., Synthesis, Structure, Photoluminescence and Theoretical Study of (MQ)(CdBr4) with MQ2+ Generated In Situ (MQ2+ = N-Me-4,4 '-bipyridinium). Journal of the Iranian Chemical Society, 2009, 6 (1), 213-218.

4.  Fang XN, et al., Facile Stereoselective Synthesis of (E)-1-Arylseleno-Substituted 1,3-Enynes and Their Applications in Synthesis of (E)-Enediynes. Synthetic Communications, 2008, 38 (23), 4170-4181.

5. Fang XN, et al., Synthesis and structural characterization of new tri (2-methyl-2-phenylpropyl) tin carboxylates containing germanium. Journal of Organometallic Chemistry, 2001,619(1-2), 43-48

6. Song LC, Fang XN, et al., Novel ?-CO-Containing Butter?y Fe/S Cluster Anions Generated from Tetrathiols, Fe3(CO)12, and Et3N: Their Reactions with Electrophiles To Give Neutral Butter?y Fe/S Cluster Complexes, Organometallics, 2008, 27, 3225–3231

7. Sui Y, et al., Syntheses, structure, redox and catalytic epoxidation properties of dioxomolybdenum(VI) complexes with Schiff base ligands derived from tris(hydroxymethyl)amino methane, J. Mol. Catal. A:Chem., 2007, 270(1-2), 61-67

8. Sui Y, et al., Grafting polyethylene glycols molybdenum(VI) complexes on ZSPP and their catalytic epoxidation of cyclohexene, Catal. Commun., 2008, 9(15), 2616-2619

9. Sui Y, et al., A new type of heterogeneous epoxidation catalysts polyamines molybdenum (VI) complexes grafted on zirconium oligo-styrenyl phosphonate hydrogen phosphate. Materials Letters, 2007, 61 (6), 1354-1357

10. Sui Y, et al., Study of preparation and reaction mechanisms of new types of phosphonous acid-teminated oligostyrene. Reactive & Functional Polymers 2005, 64 (1), 55-62

11. Sui Y, et al., Syntheses, structure, redox and catalytic epoxidation properties of dioxomolybdenum(VI) complexes with Schiff base ligands derived from tris(hydroxymethyl)amino methane. Journal of Molecular Catalysis A-Chemical2007, 270 (1-2), 61-67

12. Hu RH, et al, MCM-41-supported mercapto platinum complex as a highly efficient catalyst for the hydrosilylation of olefins with triethoxysilane. Catalysis Communications, 2009, 11 (6), 563-566

13. Hu RH, et al, Stereoselective synthesis of vinyl sulfones by the Stille coupling of (E)-alpha-stannylvinyl sulfones with aryl halides. Journal of Chemical Research-S,2008, (10), 592-594

14. Hu RH, et al, A novel stereoselective synthesis of (1Z,3E)-2-phenyl(or p-tolyl)sulfonyl-substituted 1,3-dienes via palladium catalyzed cross-coupling reactions of (E)-alpha-lodovinyl sulfones. Chinese Journal of Chemistry, 2007, 25 (12), 1927-1931.

15. Hu RH, et al, A facile stereoselective synthesis of (Z)-2-arylsulfonyl-substituted 1,3-enynes from (E)-alpha-stannylvinyl sulfones and alkynyl bromides. Journal of Chemical Research-S, 2007, (3), 173-176.

16. Tang BX, et al., Copper-Catalyzed Intramolecular C-H Oxidation/Acylation of Formyl-N-arylformamides Leading to Indoline-2,3- diones. J. Am. Chem. Soc., 2010, 132, 8900-8902.

17.  Tang BX, et al., Selective Synthesis of Spiro[4,5]trienyl Acetates via an Intramolecular Electrophilic ipso-Iodocyclization Process. Org. Lett.,2008, 10, 1063-1066.

18. Tang BX, et al., Electrophilic ipso-Cyclization of N-(p-Methoxyaryl)- propiolamides Involving an Electrophile-Exchange Process. J. Org. Chem.,2008, 73, 9008-9011.

19. Tang BX, et al., N-Arylations of Nitrogen-Containing Heterocycles with Aryl and Heteroaryl Halides Using a Copper(I) Oxide Nanoparticle/1,10- Phenanthroline Catalytic System. Synthesis., 2008, (11), 1707-1716.

20. Tang BX, et al., Reusable Cu2O/PPh /TBAB System for the Cross-Couplings of Aryl Halides and Heteroaryl Halides with Terminal Alkynes. J. Org. Chem.,2007, 72, 6294-6297.